Looks like a neat scheme; I've never seen silver/gunmetal used as a primary color for a Slaanesh army. (In 40k at least)
I think the purple looks black because of the lighting. Maybe if you had a lamp above/near the mini, you could see it better. In the third photo, you can see the purple a bit clearer than the others. I suggest experimenting with a lighter purple or adding highlights to the trim. As of now it looks darker than the scheme on the CSM painter, but I don't know what shade you're going for. I like the red, except it looks a little bright on the chest compared to the other areas. A dark red, like on the backpack might look better.
All in all, it's a nice start and I look forward to your progress! Now I just have to get some pics of my scheme this week.